Calculate elemental percent composition from chemical formulas, element masses, or mixtures. Supports hydrates, isotopic masses, empirical formula derivation, and unit conversions.
Enter a chemical formula or element masses and click Calculate to see percent composition results
Supports parentheses, nested groups, and standard chemical notation including hydrates
Calculate empirical formulas from element masses with step-by-step solutions
Override atomic masses with specific isotopes (e.g., ²H, ¹³C, ³⁷Cl)
Analyze multi-component mixtures with aggregated element composition
Percent composition by mass (also called mass percent or percentage composition) is a fundamental concept in chemistry that describes what percentage of a compound's total mass comes from each element present. It's a quantitative way to express the elemental makeup of any chemical substance—whether you're analyzing water (H₂O), glucose (C₆H₁₂O₆), or complex ionic compounds like calcium phosphate Ca₃(PO₄)₂. Understanding percent composition is essential for stoichiometry, empirical formula determination, quality control in manufacturing, and countless applications across chemistry, biology, environmental science, and materials engineering.
The concept is beautifully straightforward: if you know a compound's chemical formula, you can calculate exactly what fraction of its mass each element contributes. For example, in water (H₂O), hydrogen makes up approximately 11.2% of the total mass while oxygen accounts for 88.8%. This isn't counting atoms (where hydrogen would be 67% since there are 2 H atoms vs 1 O atom)—it's about mass distribution. Oxygen atoms are ~16 times heavier than hydrogen atoms, so despite having fewer oxygen atoms, oxygen dominates the mass. This distinction between percent by mass versus percent by atom count is crucial and trips up many students initially.
Percent composition calculations rely on molar mass (molecular weight)—the mass of one mole of a substance, expressed in grams per mole (g/mol). To find percent composition, you first determine the molar mass of the entire compound by summing the atomic masses of all constituent atoms (accounting for subscripts and parentheses). Then, for each element, you calculate the total mass contributed by that element (atomic mass × number of atoms) and divide by the compound's total molar mass, multiplying by 100 to get a percentage. The sum of all elemental mass percentages must equal 100% (within rounding error), providing a built-in check for calculation accuracy.
Real-world applications of percent composition are everywhere. In analytical chemistry, chemists use mass percent to verify compound purity and identify unknown substances by comparing experimental composition to theoretical values. In environmental science, percent composition helps quantify pollutant concentrations in air, water, and soil samples. Nutritional science conceptually uses similar principles when analyzing the elemental content of foods (though typically expressed differently). In materials science, engineers determine the composition of alloys, polymers, and ceramics to ensure proper material properties. In pharmaceutical manufacturing, precise compositional analysis ensures drug quality and dosing accuracy.
Our Percent Composition Calculator automates the tedious arithmetic while helping you understand the underlying chemistry. Simply enter a chemical formula (like NaCl, Ca(OH)₂, or CuSO₄·5H₂O for hydrates), and the calculator instantly parses the formula, identifies all elements, calculates atomic masses, computes the total molar mass, and breaks down the mass percentage for each element. It handles complex notation including parentheses, brackets, subscripts, and hydrate dots (·). The tool displays results in clear tables, highlights the distribution with visual charts, and even supports advanced features like isotopic variants (for research applications) and empirical formula determination from mass data.
Whether you're a high school chemistry student working through stoichiometry homework, a college student preparing for organic chemistry exams, a lab technician verifying experimental results, or simply someone curious about the molecular world, this calculator makes percent composition accessible and intuitive. Use it to check your manual calculations, explore "what if" scenarios, understand how formula changes affect composition, and build deep chemical intuition. Remember: this tool is for educational and conceptual purposes—in professional lab settings, always follow proper analytical procedures and instrumentation for composition analysis.
Percent composition (by mass) is the percentage of the total mass of a compound that comes from each element. It's calculated as: (mass of element / total mass of compound) × 100%. For a compound with formula CₐHᵦOᵧ, you find the mass of all carbon atoms, all hydrogen atoms, and all oxygen atoms, then express each as a percentage of the total molar mass. The percentages always sum to 100%.
Molar mass is the mass of one mole (6.022 × 10²³ formula units) of a substance, measured in grams per mole (g/mol). It's numerically equal to the sum of atomic masses of all atoms in the formula. For H₂O: molar mass = 2×(1.008 g/mol for H) + 1×(16.00 g/mol for O) = 18.016 g/mol. This is the foundation for all stoichiometric calculations and percent composition analysis.
Atomic mass (or atomic weight) is the average mass of an element's atoms, accounting for natural isotope abundance, measured in atomic mass units (amu) or g/mol. Found on the periodic table (e.g., C = 12.011, O = 15.999, Na = 22.990), atomic masses are the building blocks for calculating molar masses. Use the most precise values available for accurate percent composition—rounding too early introduces errors.
Chemical formulas use subscripts to indicate the number of each atom (H₂O has 2 hydrogens, 1 oxygen). Parentheses group atoms that appear together multiple times: Ca(OH)₂ means 1 Ca, 2 O, and 2 H (the subscript 2 outside parentheses multiplies everything inside). Brackets and braces work similarly in complex ions. Understanding how to parse formulas correctly is essential—misreading subscripts or forgetting to multiply by parentheses is a common source of errors.
Since percent composition accounts for all mass in the compound, the sum of all elemental percentages must equal 100%. If your calculations give 98% or 102%, you have a rounding error, calculation mistake, or incorrect atomic masses. This 100% check is a powerful self-verification tool—always sum your percentages and investigate discrepancies. In real experimental data, small deviations (±0.5%) can occur due to measurement uncertainty, but theoretical calculations should sum exactly to 100%.
The empirical formula shows the simplest whole-number ratio of atoms (e.g., CH₂O for glucose). The molecular formula shows the actual number of atoms (C₆H₁₂O₆ for glucose). Both have the same percent composition—a key insight! You can determine an empirical formula from percent composition by converting mass percentages to moles, finding mole ratios, and simplifying. Percent composition is the bridge between experimental mass data and chemical formulas.
Hydrates are ionic compounds that incorporate water molecules into their crystal structure, written with a dot: CuSO₄·5H₂O (copper(II) sulfate pentahydrate). The water contributes to total mass and affects percent composition. For example, the 5H₂O adds 90 g/mol to CuSO₄'s 159.6 g/mol, making the hydrate 249.6 g/mol—water is 36% of the total mass. This calculator handles hydrate notation seamlessly, crucial for accurate analysis of crystalline compounds.
This calculator is designed for maximum flexibility—whether you're analyzing a simple binary compound or a complex hydrated salt with nested parentheses. Here's a comprehensive step-by-step guide:
In the main input field, type the chemical formula of your compound. The calculator accepts:
Example inputs:
H2O → Water
Ca(OH)2 → Calcium hydroxide
Fe2O3 → Iron(III) oxide
C6H12O6 → Glucose
Pro tip: Use uppercase for the first letter of element symbols (Ca, not ca) and lowercase for the second (Cl, not CL). Subscripts can be typed as regular numbers (H2O works as well as H₂O).
Depending on your calculator's features, you may have multiple modes:
For basic percent composition problems, use "From Formula" mode. For determining an unknown compound's formula from lab data, use "From Element Masses".
Some calculators allow you to set decimal precision (e.g., 2, 3, or 4 decimal places). For homework, 2-3 decimals usually suffice (e.g., 11.19% for hydrogen in water). For research or when matching significant figures from given data, use higher precision. Remember: your answer's precision should match your input data's precision (significant figures rule).
Hit the "Calculate" button. The calculator will:
Example result for H₂O:
Molar Mass: 18.015 g/mol
H: 2 atoms × 1.008 g/mol = 2.016 g → 11.19%
O: 1 atom × 15.999 g/mol = 15.999 g → 88.81%
Total: 11.19% + 88.81% = 100.00% ✓
Always perform sanity checks:
If results look wrong, recheck your formula for typos (common: typing O instead of 0, lowercase l instead of uppercase I).
Use the "Copy Result" button to paste results into your homework, lab report, or notes. Use "Copy as CSV" to export data to Excel/Sheets for further analysis or graphing. Save results as reference for multi-part problems. For empirical formula problems, use the calculated percentages as verification: if you derive CH₂O from mass data, check that its theoretical composition matches your input percentages.
Understanding the math empowers you to solve problems by hand, verify calculator results, and build chemical intuition. Here's the complete mathematical framework:
% Element = (Mass of Element / Total Molar Mass) × 100%
Mass of Element: (Atomic mass of element) × (Number of atoms of that element)
Total Molar Mass: Sum of (atomic mass × number of atoms) for all elements
This formula is applied to each element in the compound. The numerator is the total mass contributed by that element, and the denominator is the mass of the entire formula unit.
Step A: Identify all elements and their quantities
Parse the formula, accounting for subscripts and parentheses. For Ca(OH)₂: 1 Ca, 2 O, 2 H
Step B: Look up atomic masses
Ca = 40.078 g/mol, O = 15.999 g/mol, H = 1.008 g/mol
Step C: Calculate mass of each element
Ca: 1 × 40.078 = 40.078 g/mol
O: 2 × 15.999 = 31.998 g/mol
H: 2 × 1.008 = 2.016 g/mol
Step D: Calculate total molar mass
Total = 40.078 + 31.998 + 2.016 = 74.092 g/mol
Step E: Calculate percent composition for each element
% Ca = (40.078 / 74.092) × 100% = 54.09%
% O = (31.998 / 74.092) × 100% = 43.18%
% H = (2.016 / 74.092) × 100% = 2.72%
Step F: Verify sum = 100%
54.09% + 43.18% + 2.72% = 99.99% ≈ 100% ✓ (rounding)
Problem: Calculate percent composition of glucose, C₆H₁₂O₆
Step 1: Identify elements and quantities
C: 6 atoms, H: 12 atoms, O: 6 atoms
Step 2: Atomic masses (from periodic table)
C = 12.011 g/mol, H = 1.008 g/mol, O = 15.999 g/mol
Step 3: Mass of each element
C: 6 × 12.011 = 72.066 g/mol
H: 12 × 1.008 = 12.096 g/mol
O: 6 × 15.999 = 95.994 g/mol
Step 4: Total molar mass
Total = 72.066 + 12.096 + 95.994 = 180.156 g/mol
Step 5: Percent composition
% C = (72.066 / 180.156) × 100% = 40.00%
% H = (12.096 / 180.156) × 100% = 6.71%
% O = (95.994 / 180.156) × 100% = 53.29%
Answer:
Glucose is 40.00% carbon, 6.71% hydrogen, 53.29% oxygen by mass
Check: 40.00 + 6.71 + 53.29 = 100.00% ✓
Problem: Find percent composition of calcium hydroxide, Ca(OH)₂
Parse formula (parentheses!):
Ca: 1 atom
O: 2 atoms (subscript 2 outside parentheses)
H: 2 atoms (subscript 2 outside parentheses)
Atomic masses:
Ca = 40.078, O = 15.999, H = 1.008 g/mol
Element masses:
Ca: 1 × 40.078 = 40.078 g/mol
O: 2 × 15.999 = 31.998 g/mol
H: 2 × 1.008 = 2.016 g/mol
Total: 74.092 g/mol
Percentages:
% Ca = (40.078 / 74.092) × 100% = 54.09%
% O = (31.998 / 74.092) × 100% = 43.18%
% H = (2.016 / 74.092) × 100% = 2.72%
Key insight: Don't forget to multiply atoms inside parentheses by the subscript outside!
Given percent composition, you can determine the empirical formula:
Example: A compound is 40.0% C, 6.7% H, 53.3% O. Find empirical formula.
Assume 100 g: 40.0 g C, 6.7 g H, 53.3 g O
Moles: C = 40.0/12.011 = 3.33 mol
H = 6.7/1.008 = 6.65 mol
O = 53.3/15.999 = 3.33 mol
Divide by smallest (3.33): C = 1, H = 2, O = 1
Empirical formula: CH₂O (formaldehyde, or glucose/sugars)
Percent composition isn't just a homework exercise—it's a fundamental analytical tool used across science and industry. Here are detailed real-world scenarios:
Scenario: A pharmaceutical company receives a shipment of sodium chloride (NaCl) for IV solution manufacturing. Theoretical NaCl is 39.34% Na, 60.66% Cl. Lab analysis shows 39.1% Na, 60.4% Cl (slightly different, within measurement error), confirming high purity. If composition were significantly off (e.g., 35% Na), it would indicate contamination or wrong compound. Percent composition is a first-line quality check in manufacturing—use the calculator to compute theoretical values for comparison with experimental results. This prevents defective products from reaching consumers.
Scenario: Your organic chemistry lab burns an unknown hydrocarbon, collects CO₂ and H₂O, and determines the sample was 85.7% C, 14.3% H by mass. Using the reverse calculation method (percent → moles → ratio), you find: C = 85.7/12.011 = 7.13 mol, H = 14.3/1.008 = 14.2 mol. Ratio: 7.13:14.2 ≈ 1:2 → empirical formula CH₂. This could be ethylene (C₂H₄), propylene (C₃H₆), or any (CH₂)ₙ polymer. Molecular formula requires additional data (molar mass from mass spectrometry). Percent composition is the foundation for identifying unknown organic compounds in research and forensics.
Scenario: A bag of ammonium nitrate fertilizer (NH₄NO₃) is labeled "35% nitrogen." You verify: NH₄NO₃ has 2 N atoms (one in NH₄⁺, one in NO₃⁻). N mass = 2 × 14.007 = 28.014 g/mol. Total molar mass = 80.043 g/mol. % N = (28.014 / 80.043) × 100% = 35.00% ✓. The label is correct. Farmers rely on accurate N percentages to calculate fertilizer application rates. Too much wastes money and pollutes runoff; too little reduces crop yield. Percent composition ensures agricultural products deliver advertised nutrient levels.
Scenario: Lab stockroom has copper(II) sulfate pentahydrate, CuSO₄·5H₂O (blue crystals). You need anhydrous CuSO₄ (white powder) for a reaction. Question: If you heat 10 g of CuSO₄·5H₂O to drive off water, how much anhydrous CuSO₄ remains? Calculate percent water: molar mass of hydrate = 249.68 g/mol, molar mass of 5H₂O = 90.08 g/mol. % water = (90.08 / 249.68) × 100% = 36.08%. So 10 g × (100% − 36.08%) = 6.39 g anhydrous salt. Percent composition is critical for stoichiometry involving hydrates, common in inorganic and analytical chemistry labs.
Scenario: Your chemistry homework asks: "Find percent composition of sulfuric acid, H₂SO₄." You calculate by hand: H = 2.06%, S = 32.69%, O = 65.25%. Total = 100.00% ✓. To double-check (because exam is tomorrow and you can't afford errors), input H2SO4 into this calculator. It returns: H = 2.06%, S = 32.69%, O = 65.25%. Perfect match—confidence boosted! Use the calculator as a study tool: work problems manually, then verify. This builds skill AND accuracy, the winning combination for academic success.
Scenario: Your research lab synthesizes a new compound. Mass spec gives molar mass = 180 g/mol. Elemental analysis shows 40% C, 6.7% H, 53.3% O. You calculate empirical formula (from earlier example): CH₂O, molar mass 30 g/mol. Since 180 / 30 = 6, molecular formula is C₆H₁₂O₆. Searching a database, this matches glucose, fructose, and other hexoses. Further analysis (NMR, IR) identifies which isomer. Percent composition narrows possibilities from infinite compounds to a handful, accelerating identification in organic synthesis and natural product chemistry.
Scenario: Environmental chemists sample air particulates, finding lead(II) oxide (PbO) contamination. To calculate lead exposure, they need % Pb. Molar mass PbO = 207.2 (Pb) + 16.0 (O) = 223.2 g/mol. % Pb = (207.2 / 223.2) × 100% = 92.8%. If air has 10 μg/m³ PbO, it contains 9.28 μg/m³ elemental Pb. Regulations limit Pb exposure, so converting compound concentrations to elemental concentrations via percent composition is essential for environmental health assessments and compliance monitoring.
Scenario: Metallurgists design a steel alloy with specific properties. Recipe calls for Fe₃C (cementite) to provide hardness. They calculate % carbon: molar mass Fe₃C = 3×55.845 + 12.011 = 179.546 g/mol. % C = (12.011 / 179.546) × 100% = 6.69%. Knowing this, they can determine how much carbon to add to molten iron to achieve desired cementite content, predicting hardness, brittleness, and strength. Percent composition links microscopic formula to macroscopic properties, essential in materials engineering for everything from skyscraper beams to surgical instruments.
Even straightforward percent composition problems can go wrong if you're not careful. Here are the top errors students and practitioners make, with solutions:
Mistake: For Ca(NO₃)₂, counting only 1 N and 3 O instead of 2 N and 6 O.
Why it's wrong: The subscript 2 outside parentheses applies to everything inside: (NO₃)₂ = N₂O₆. Forgetting this multiplier dramatically changes composition.
Solution: Always expand parentheses first. Ca(NO₃)₂ = 1 Ca + 2 N + 6 O. Write it out explicitly before calculating masses.
Mistake: Saying H₂O is 67% hydrogen because 2 out of 3 atoms are hydrogen.
Why it's wrong: Percent composition is by mass, not atom count. Oxygen atoms are 16× heavier than hydrogen, so despite fewer O atoms, O dominates mass (~89%).
Solution: Always calculate using masses (atomic mass × count), never just atom ratios. Mass and atoms are different metrics.
Mistake: Rounding C = 12.011 to 12, O = 15.999 to 16 at the start, then getting percentages that don't sum to 100%.
Why it's wrong: Rounding introduces cumulative error. For complex formulas, this can cause 1-2% discrepancies.
Solution: Use full atomic masses (at least 3-4 decimals) throughout calculations. Round only the final percentage to 2-3 decimals.
Mistake: Reading Al₂O₃ as AlO₃ or Al₂O (ignoring subscripts), or confusing O (oxygen) with 0 (zero).
Why it's wrong: Subscripts define the formula; wrong subscripts = wrong compound = wrong composition.
Solution: Double-check formula before calculating. Write it clearly. Distinguish O (letter) from 0 (number), I (iodine) from l (lowercase L).
Mistake: Calculating composition of CuSO₄·5H₂O using only CuSO₄ molar mass, forgetting the 5H₂O.
Why it's wrong: The hydrate dot (·) means the water is part of the crystal structure and must be included in total mass.
Solution: Treat hydrates as a single formula unit: add molar masses of anhydrous compound AND water. CuSO₄·5H₂O = 159.6 + 90.08 = 249.68 g/mol.
Mistake: Getting 45% C, 50% O, and thinking "close enough" without noticing 5% is missing (forgot hydrogen).
Why it's wrong: Missing mass indicates an overlooked element or calculation error. Percentages MUST sum to 100% (±0.1% for rounding).
Solution: Always sum percentages as a final check. If ≠ 100%, revisit formula parsing, atomic masses, and arithmetic. This is your error-detection alarm.
Mistake: Thinking empirical formula CH₂O and molecular formula C₆H₁₂O₆ have different percent compositions.
Why it's wrong: Empirical and molecular formulas in the same ratio have identical percent compositions. CH₂O and C₆H₁₂O₆ both are 40% C, 6.7% H, 53.3% O.
Solution: Remember: percent composition depends on elemental ratios, not absolute numbers. Simplifying the formula doesn't change mass percentages.
Mistake: Using C = 12.00 (old value) instead of 12.011 (current IUPAC standard), causing small but cumulative errors.
Why it's wrong: Atomic masses are periodically updated as measurement precision improves. Old values reduce accuracy.
Solution: Use a current periodic table or the calculator's built-in atomic masses (which are kept up-to-date). For exams, use the values provided by your instructor.
Mistake: Reading Pb (lead, 207.2 g/mol) as P (phosphorus, 30.97 g/mol), completely changing composition.
Why it's wrong: Different elements have vastly different atomic masses. Symbol confusion = wrong element = nonsense results.
Solution: Know your element symbols cold. Pb = lead (from Latin plumbum), P = phosphorus. When in doubt, check periodic table. Precision matters.
Mistake: Calculating mass of element (e.g., 40.078 g Ca) and total mass (74.092 g), then reporting "40.078" as the percentage instead of 54.09%.
Why it's wrong: You forgot the final step: divide and multiply by 100. A ratio isn't a percentage until you convert it to per-hundred.
Solution: Always include the "× 100%" step. Use units throughout: (40.078 g / 74.092 g) × 100% = 54.09%. Units help you remember.
Once you've mastered basic percent composition, these advanced techniques will deepen your understanding and prepare you for complex chemistry problems:
Technique: Before calculating, estimate. "H₂O: oxygen is ~16× heavier than hydrogen. With 2 H vs 1 O, O should be ~90%, H ~10%." Do full calculation, get 88.81% and 11.19%—close! This intuitive sense helps you catch errors instantly. If you calculate 50% H in water, you know something's wrong immediately without needing the calculator to verify.
Strategy: After determining an empirical formula from mass data, calculate its theoretical percent composition and compare with your starting percentages. They should match (within rounding). This bidirectional check—forward (formula → %) and backward (% → formula → %) —catches errors in either direction and solidifies your understanding of the relationship between formulas and composition.
Insight: Isomers (same molecular formula, different structures) have identical percent composition. Glucose and fructose (both C₆H₁₂O₆) are both 40% C, 6.7% H, 53.3% O despite different properties. But constitutional isomers with different formulas (e.g., ethanol C₂H₆O vs dimethyl ether C₂H₆O—wait, same formula, so same composition!) show how composition doesn't reveal structure. This teaches the limits of composition analysis: it identifies elemental makeup but not arrangement.
Application: Stoichiometry problems often require converting between mass and moles. Percent composition skills translate directly: finding moles of an element in a compound is essentially a composition problem. For 50 g of Fe₂O₃ (69.94% Fe), mass of Fe = 50 × 0.6994 = 34.97 g, then convert to moles. This linkage makes stoichiometry easier because you see it as an extension of composition analysis, not a separate topic.
Precision rule: Your final percentage precision should match your input atomic mass precision. If atomic masses have 4 sig figs (12.011), report percentages to 4 sig figs (40.00%). For homework, typically 3-4 sig figs suffice. In research with high-precision mass spec, 5-6 decimals might be needed. Understanding when to round—and when not to—separates good chemists from excellent ones. Practice matching sig figs to measurement precision.
Lab connection: When heating hydrated salts, you can determine the degree of hydration (the "n" in CuSO₄·nH₂O) from mass loss. If 2.50 g CuSO₄·nH₂O loses 0.90 g when heated, that 0.90 g is water. Percent water = (0.90 / 2.50) × 100% = 36%. Compare to theoretical values for different n (for n=5, theoretical is 36.08%)—you confirm n=5. This practical use of percent composition in lab work makes the concept tangible and reinforces the theory-experiment connection.
Specialized technique: In isotope labeling studies (biology, medicine, geochemistry), you might calculate composition using specific isotopes. For deuterium-labeled water (²H₂O or D₂O), use mass 2.014 for D instead of 1.008 for H. Molar mass becomes 20.028 g/mol vs 18.015 for regular water. This shifts percent composition: D = 20.1%, O = 79.9%. Such calculations are crucial in metabolic tracer studies, NMR spectroscopy prep, and climate science (δ¹⁸O paleothermometry). The calculator's isotope feature enables these advanced analyses.
Pattern recognition: Calculate composition for a series: CH₄, C₂H₆, C₃H₈, C₄H₁₀ (alkanes). Notice % C increases (75% → 80% → 82% → 83%) while % H decreases (25% → 20% → 18% → 17%) as chain lengthens, approaching ~86% C for long chains. Understanding these trends helps you predict properties, recognize compound classes, and develop chemical intuition. Use the calculator to explore series (oxides, alcohols, acids) and discover compositional patterns chemistry students rarely see.
Environmental application: Regulations limit elemental pollutants (e.g., "10 ppm lead"). Pollutants exist as compounds (PbO, PbSO₄). Convert compound concentration to element using percent composition: if air has 15 μg/m³ PbSO₄ (68.3% Pb), elemental Pb = 15 × 0.683 = 10.2 μg/m³. This conversion is essential for regulatory compliance, risk assessment, and environmental monitoring. Percent composition bridges measured compounds to regulated elements.
Study strategy: Create a "cheat sheet" (for study, not exams!) with percent compositions of common compounds: H₂O, CO₂, NaCl, CaCO₃, H₂SO₄, glucose, ethanol, etc. Memorizing a few (~10-15) gives you instant reference points. When you calculate an unknown and get values near a memorized compound, you can identify it or catch errors. This compound literacy accelerates problem-solving and builds confidence. Start with compounds from your current course, expand as you progress.
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